Inorganic Chemistry (Theory)

Paper Code: 
CNST 103
Credits: 
04
Contact Hours: 
60.00
Max. Marks: 
100.00
Objective: 

Course Objectives:    

This course will enable the students to –

  1. recall the general trends in the periodic table of elements.
  2. equip with the knowledge of gradation in properties of main group elements and theoretical concepts of different titrations of volumetric analysis like principle, applications and indicators used etc.

 

 

Course Outcomes (COs):

Course

Learning outcomes

(at course level)

Learning and teaching strategies

Assessment

Strategies

Course Code

Course Title

CNST 103

Inorganic Chemistry (Theory)

The students will be able to –

 

CO:1. explain Bohr’s theory and concept of wave function and quantum numbers

 

CO:2. calculate the radius ratio of ionic molecules and determine the ionic structures of the type AX and AX2

 

CO:3. appraise the concept of Born-Haber cycle and predict the lattice energy, ionization energy and stability of the ionic compounds.

 

CO:4. predict physical and chemical characteristics of elements in various groups and periods according to ionic size, charge, etc. and position in periodic table and describe various types of hybridization and geometry of molecules.

 

CO:5. construct molecular orbital diagrams of homo and hetero nuclear diatomic molecules and determine the bond order with the help of M.O. diagram.

 

CO:6. discuss the different theories of metallic bonding, hydrogen bonding and Van der Waals interaction.

 

Approach in teaching:

 

Interactive sessions, Discussion, problem solving in Tutorials,  Demonstration

 

Learning activities for the students:

Self-learning assignments, Effective questions, Simulation, Seminar presentation, Solving numericals.

 

 

 

Class test, Semester end examinations, Quiz, Solving problems, Assignments, Presentations

 

 

 

12.00
Unit I: 
Atomic Structure

Bohr’s theory to hydrogen-like atoms and ions; spectrum of hydrogen atom. Quantum numbers. Introduction to the concept of atomic orbitals; shapes, radial and angular probability diagrams of s, p and d orbitals (qualitative idea). Many electron atoms and ions: Pauli’s exclusion principle, Hund’s rule, exchange energy, Aufbau principle and its limitation. Electronic energy level diagram and electronic configurations of hydrogen-like and polyelectronic atoms and ions up to atomic number 

10.00
Unit II: 
Chemical Periodicity

Periodic table, group trends and periodic trends in physical properties.Classification of elements on the basis of electronic configuration. Modern IUPAC Periodic table. General characteristic of s, p, d and f block elements. Position of hydrogen and noble gases in the periodic table. Effective nuclear charges, screening effects, Slater’s rules, atomic radii, ionic radii (Pauling’s univalent), covalent radii. Ionization potential, electron affinity and electronegativity (Pauling, Mulliken and Allred-Rochow scales) and factors influencing these properties. Inert pair effect. 

10.00
Unit III: 
Ionic Bonding
Size effects, radius ratio rules and their limitations. Packing of ions in crystals, ionic compounds of the type AX (ZnS, NaCl, CsCl) and AX2 (CaF2-fluorite) lattice energy, Born–Landéequation and its applications, Born-Haber cycle and its applications. Solvation energy, polarizing power and polarizability, ionic potential,Fajans’ rules. Defects in solids.
 
12.00
Unit IV: 
Covalent Bonding

Lewis structures, formal charge. Valence Bond Theory, directional character of covalent bonds, hybridizations, equivalent and non-equivalent hybrid orbitals, Bent’s rule, VSEPR theory, shapes of molecules and ions containing lone pairs and bond pairs (examples from main groups chemistry), partial ionic character of covalent bonds, bond moment, dipole moment and electronegativity differences. Concept of resonance, resonance energy, resonance structures.

16.00
Unit V: 
Other Types of Bonding
Molecular orbital concept of bonding (elementary pictorial approach), eg ( O2 and C2 )sigma and pi-bonds, multiple bonding; bond orders, bond lengths, 
Coordinate bonding: double salts and complex salts, Werner’s coordination theory, IUPAC nomenclature and isomerism in complex compounds, Lewis acid-base adducts.
Hydrogen bonding: effect on the physical properties of compounds of the main group elements.
Metallic bonding: qualitative idea of band theory, conducting, semi conducting and insulating properties with examples from main group elements.
References: 
1. Concise Inorganic Chemistry; Fifth Edition; J.D. Lee; Wiley India (P) Ltd, New Delhi, 2008. 
2. Inorganic Chemistry; Seventh International Edition; M. Weller, T.Overton, J. Rourke, F. Armstrong; Oxford University Press, New York, 2018.
3. Vogel’s Textbook of Quantitative Chemical Analysis; Sixth Edition; M. Thomas, B. Sivasankar, J. Mendham, R.C. Denney, J. D. Barnes; Pearson Education, New Delhi, 2009.
 
Academic Year: